Neymar has 128 caps and a record 79 goals for his country, surpassing Pele's tally of 77.
Neymar admitted he was taken aback by the request from someone widely regarded as one of the greatest footballers of all time.
After a gap of 502 days, Brazilian superstar Neymar finally found the back of the net when he converted from the spot for Santos in their 3-1 win over Agua Santa in the Sao Paulo State Championship today.
Brazilian superstar Neymar recently moved back to his boyhood club Santos after an underwhelming stint with Saudi Pro League Club Al Hilal.
The Urbano Caldeira stadium erupted in celebration as jubilant and tearful fans lit up their mobile phones to give the striker, who left the club 12 years ago, a hero's welcome before kick-off.
Neymar has been one of the finest players in the world when at the top of his game, a forward with dazzling skill who "understands football as art", as his former Barcelona coach Luis Enrique once said.
Neymar has been one of the finest players in the world when at the top of his game, a forward with dazzling skill who "understands football as art", as his former Barcelona coach Luis Enrique once said.
The 32-year-old former Barcelona and Paris Saint-Germain forward played just seven times for Al Hilal despite a reported salary of around $104 million a year.
Santos' president told Brazilian superstar Neymar it was "time to return to (his) people" in a video published on social media on Tuesday.
Brazilian superstar Neymar is reportedly ready to accept a huge pay cut to facilitate a return to his boyhood club Santos and the booter is likely to complete the move soon.
The 32-year-old former Barcelona and Paris Saint-Germain forward has had an injury-plagued stay in Saudi Arabia, playing just seven times despite a reported salary of around $104 million a year.
Speaking on a podcast hosted by former Brazil striker Romario, Neymar blamed a clash of egos for the failure of the three stars to gel during their spell together at the French club.
Rumours linking Neymar with a move to Miami to recreate the old 'MSN' Barcelona front line with Messi and Luis Suarez have resurfaced in recent days.
The Brazilian does not rule out reuniting with former Barcelona team-mates Lionel Messi and Luis Suarez at Inter Miami.
Neymar was out for more than a year until last month following right knee surgery.
The Brazilian superstar lasted just 26 minutes as a second-half substitute before limping off with an apparent right hamstring strain in Monday's 3-0 AFC Champions League Elite win over Esteghlal.
The evening ended on a sour note for Al-Hilal when Neymar, who returned two weeks ago from a year out due to a ruptured cruciate ligament, was replaced 29 minutes after his introduction from the bench due to injury.
The former Barcelona and Paris Saint-Germain attacker had not played since rupturing his meniscus and anterior cruciate ligament in his left knee while on international duty in October last year.
"Happy to be back in the group," Neymar posted on Instagram, with pictures of him running and kicking the ball, watched by Al Hilal's Portuguese coach Jorge Jesus.